TRISPHAT-N: A Chiral Hexacoordinated Phosphate Anion with Unique Asymmetric Coordinating Properties

Constant, Samuel Claude; Frantz, Richard; Müller, Jessica; Bernardinelli, Gérald Hugues; Lacour, Jérôme

doi:10.1021/om070074k

Scientific article

English

TRISPHAT-N: A Chiral Hexacoordinated Phosphate Anion with Unique Asymmetric Coordinating Properties

ContributorsConstant, Samuel Claude; Frantz, Richard; Müller, Jessica; Bernardinelli, Gérald Hugues; Lacour, Jérôme

Published inOrganometallics, vol. 26, no. 9, p. 2141-2143

Publication date2007

Abstract

A simple and efficient chiral anionic N-ligand: the introduction of a Lewis basic nitrogen onto the TRISPHAT skeleton allows the direct and efficient stereocontrol of tropos chiral ligands bound to metal complexes or of stereogenic metal centers (dr up to 96:4).

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

CONSTANT, Samuel Claude et al. TRISPHAT-N: A Chiral Hexacoordinated Phosphate Anion with Unique Asymmetric Coordinating Properties. In: Organometallics, 2007, vol. 26, n° 9, p. 2141–2143. doi: 10.1021/om070074k

Article

Identifiers

PID : unige:6934
DOI : 10.1021/om070074k

Journal ISSN0276-7333

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TRISPHAT-N: A Chiral Hexacoordinated Phosphate Anion with Unique Asymmetric Coordinating Properties

A simple and efficient chiral anionic N-ligand: the introduction of a Lewis basic nitrogen onto the TRISPHAT skeleton allows the direct and efficient stereocontrol of tropos chiral ligands bound to metal complexes or of stereogenic metal centers (dr up to 96:4).

Technical informations