New Staves for Old Barrels: Regioisomeric (12,22,33,42,53,62,73,82)-p-Octiphenyl Rods with an NMR Tag

Ronan, Dawn; Jeannerat, Damien; Pinto, André; Sakai, Naomi; Matile, Stefan

doi:10.1039/b512276g

Scientific article

English

New Staves for Old Barrels: Regioisomeric (12,22,33,42,53,62,73,82)-p-Octiphenyl Rods with an NMR Tag

ContributorsRonan, Dawn; Jeannerat, Damien; Pinto, André; Sakai, Naomi

; Matile, Stefan

Published inNew Journal of Chemistry, vol. 30, no. 2, p. 168-176

Publication date2006

Abstract

The usefulness of rigid-rod p-octiphenyls with the novel 12,22,33,42,53,62,73,82-motif as staves in rigid-rod β-barrel pores is evaluated. Comparison with the known characteristics of isomeric pores with the common 13,23,32,43,52,63,72,83-sequence indicates that the self-assembly and the supramolecular chirality of rigid-rod β-barrels are independent of the substitution pattern of the p-octiphenyl stave. NMR tags added at the rod termini are shown to facilitate product characterization.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

RONAN, Dawn et al. New Staves for Old Barrels: Regioisomeric (12,22,33,42,53,62,73,82)-p-Octiphenyl Rods with an NMR Tag. In: New Journal of Chemistry, 2006, vol. 30, n° 2, p. 168–176. doi: 10.1039/b512276g

Article

Identifiers

PID : unige:6924
DOI : 10.1039/b512276g

630views

0downloads

Creation18/06/2010 08:54:22

First validation18/06/2010 08:54:22

Update time14/10/2025 06:58:58

Status update14/03/2023 15:30:17

Last indexation16/02/2026 06:55:28

Archive ouverte UNIGE

New Staves for Old Barrels: Regioisomeric (12,22,33,42,53,62,73,82)-p-Octiphenyl Rods with an NMR Tag

Technical informations