New Chromium Carbonyl Catalysts for [6+2] Cycloaddition Reactions

Kundig, Ernst Peter; Robvieux, Fabrice; Kondratenko, Mikhail

doi:10.1055/s-2002-34393

Article scientifique

Anglais

New Chromium Carbonyl Catalysts for [6+2] Cycloaddition Reactions

Contributeurs/tricesKundig, Ernst Peter; Robvieux, Fabrice; Kondratenko, Mikhail

Publié dansSynthesis, no. 14, no. 14 (Sp. Iss.), p. 2053-2056

Date de publication2002

Résumé

The complexes, (benzene)chromiumdicarbonyl(methyl acrylate) and chromiumdicarbonylbis(cyclohexadiene), are precursors for the highly coordinatively unsaturated chromium dicarbonyl fragment 3, a catalyst for the cycloaddition of activated olefins to cycloheptatriene.

Mots-clés

(arene)Cr(CO)3 Complexes
Higher order cycloaddition
Acrylate
Diene chromium complex

Structure d'affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (format ISO)

KUNDIG, Ernst Peter, ROBVIEUX, Fabrice, KONDRATENKO, Mikhail. New Chromium Carbonyl Catalysts for [6+2] Cycloaddition Reactions. In: Synthesis, 2002, n° 14, p. 2053–2056. doi: 10.1055/s-2002-34393

Identifiants

PID : unige:6610
DOI : 10.1055/s-2002-34393

ISSN du journal0039-7881

512vues

0téléchargements

Création17/05/2010 14:50:00

Première validation17/05/2010 14:50:00

Heure de mise à jour14/03/2023 15:29:04

Changement de statut14/03/2023 15:29:04

Dernière indexation15/01/2024 19:58:41

Archive ouverte UNIGE

New Chromium Carbonyl Catalysts for [6+2] Cycloaddition Reactions

The complexes, (benzene)chromiumdicarbonyl(methyl acrylate) and chromiumdicarbonylbis(cyclohexadiene), are precursors for the highly coordinatively unsaturated chromium dicarbonyl fragment 3, a catalyst for the cycloaddition of activated olefins to cycloheptatriene.

Informations techniques