Synthesis, resolution, and stabilities of a cationic chromenoxanthene [4]helicene

Guin, Joyram; Besnard, Céline; Lacour, Jérôme

doi:10.1021/ol1003466

Scientific article

English

Synthesis, resolution, and stabilities of a cationic chromenoxanthene [4]helicene

ContributorsGuin, Joyram; Besnard, Céline; Lacour, Jérôme

Published inOrganic letters, vol. 12, no. 8, p. 1748-1751

Publication date2010

Abstract

1,13-Dimethoxychromenoxanthenium, a key intermediate in the synthesis of the classical trioxatriangulenium cation, was isolated and characterized for the first time. This [4]helicene was resolved through a CSP-HPLC procedure, with chemical and configurational stabilities being determined and compared.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

GUIN, Joyram, BESNARD, Céline, LACOUR, Jérôme. Synthesis, resolution, and stabilities of a cationic chromenoxanthene [4]helicene. In: Organic letters, 2010, vol. 12, n° 8, p. 1748–1751. doi: 10.1021/ol1003466

Article (Published version)

Identifiers

PID : unige:6001
DOI : 10.1021/ol1003466

Journal ISSN1523-7052

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Synthesis, resolution, and stabilities of a cationic chromenoxanthene [4]helicene

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