Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative

Cantat, Thibault; Biaso, Frédéric; Momin, Aurélien; Ricard, Louis; Geoffroy, Michel; Mézailles, Nicolas; Le Floch, Pascal

doi:10.1039/b715380e

Scientific article

English

Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative

ContributorsCantat, Thibault; Biaso, Frédéric; Momin, Aurélien; Ricard, Louis; Geoffroy, Michel; Mézailles, Nicolas; Le Floch, Pascal

Published inChemical communications, no. 7, p. 874-876

Publication date2008

Abstract

A new type of stable radical ligand featuring a 1,1-bis-phosphinosulfide alkene backbone has been prepared and characterized on the basis of X-ray diffraction, EPR and DFT studies.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Citation (ISO format)

CANTAT, Thibault et al. Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative. In: Chemical communications, 2008, n° 7, p. 874–876. doi: 10.1039/b715380e

Article (Published version)

Identifiers

PID : unige:42
DOI : 10.1039/b715380e

Additional URL for this publicationhttp://www.rsc.org/ej/CC/2008/b715380e.pdf

Journal ISSN1359-7345

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Creation10/29/2008 11:37:42 AM

First validation10/29/2008 11:37:42 AM

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Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative

A new type of stable radical ligand featuring a 1,1-bis-phosphinosulfide alkene backbone has been prepared and characterized on the basis of X-ray diffraction, EPR and DFT studies.

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