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Crystal structures of Eu(II) substituted barium magnesium fluorides: Ba0.78(3)Eu0.22(3)MgF4 and Ba5.20(6)Eu0.80(6)Mg7F26

Published inZeitschrift für Kristallographie, vol. 214, p. 139-142
Publication date1999
Abstract

Barium in BaMgF[4] and in Ba[6]Mg[7]F[26] can be partially replaced by Sr or Eu. The single crystal structural analysis of the title compounds (a = 409.06 pm, b = 1452.7 pm, c = 579.02 pm, space group Cmc2[1] for Ba[0.78(3)]Eu[0.22(3)]MgF[4] [Z = 2, R[w] = 0.023 for 998 reflections] and a = 583.47 pm, b = 1209.09 pm and c = 1506.56 pm, space group Immm for Ba[5.20(6)]Eu[0.80(6)]Mg[7]F[26]) MgF[4] [Z = 2, R[w] = 0.019 for 2694 reflections] confirms the substitution of barium by europium. A split refinement of the substituted barium site in both crystals reveals a trend of europium to get closer to the nearest fluoride neighbors by simultaneously reducing the coordination sphere.

Keywords
  • Experimental study
  • XRD
  • Crystal structure
  • Barium fluorides
  • Magnesium fluorides
  • Europium fluorides
  • Ion substitution
  • Chemical composition
  • Inorganic compounds
  • Rare earth compounds
Research groups
Citation (ISO format)
KUBEL, Frank, HAGEMANN, Hans-Rudolf, BILL, Hans. Crystal structures of Eu(II) substituted barium magnesium fluorides: Ba0.78(3)Eu0.22(3)MgF4 and Ba5.20(6)Eu0.80(6)Mg7F26. In: Zeitschrift für Kristallographie, 1999, vol. 214, p. 139–142. doi: 10.1524/zkri.1999.214.3.139
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Article (Published version)
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Journal ISSN0044-2968
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