Scientific article
OA Policy
English

Antiaromaticity in Bare Deltahedral Silicon Clusters Satsifying Wade's and Hirsch's Rules: An Apparent Correlation of Antiaromaticity with High Symmetry

Published inJournal of the American Chemical Society, vol. 126, no. 2, p. 430-431
Publication date2004
Abstract

Entirely unlike the aromatic closo B[n]H[n][2-] borane dianions, isoelectronic Si[6][2-] and Si[12][2-] are antiaromatic. Their O[h] and I[h] symmetries are responsible, as the other deltahedral silicon dianion clusters do not exhibit this behavior. These high symmetries prevent mixing among the degenerate lone pair and skeletal orbitals, leading to paratropic behavior.

Keywords
  • Aromaticity
  • Inorganic cluster
Research groups
Citation (ISO format)
KING, R. Bruce et al. Antiaromaticity in Bare Deltahedral Silicon Clusters Satsifying Wade’s and Hirsch’s Rules: An Apparent Correlation of Antiaromaticity with High Symmetry. In: Journal of the American Chemical Society, 2004, vol. 126, n° 2, p. 430–431. doi: 10.1021/ja036259+
Main files (1)
Article (Published version)
accessLevelPublic
Identifiers
Journal ISSN0002-7863
692views
523downloads

Technical informations

Creation02/10/2009 15:17:35
First validation02/10/2009 15:17:35
Update time14/03/2023 15:15:06
Status update14/03/2023 15:15:06
Last indexation10/06/2025 21:29:08
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack