An O-2 molecule ion in CaF2: Structure and dynamical features

Bill, Hans

doi:10.1063/1.437243

Scientific article

English

An O^-₂ molecule ion in CaF₂: Structure and dynamical features

ContributorsBill, Hans

Published inThe Journal of chemical physics, vol. 70, no. 1, p. 277-283

Publication date1979

Abstract

This experimental study reports EPR and ENDOR results of an O^-₂ molecule ion in natural yellow fluorites. The O^-₂ is associated with a sodium neighbor and a calcium neighbor. This cluster performs a rapid switching movement between energetically equivalent positions. The resulting dynamical features in the EPR spectrum are investigated with the aid of the stochastic Liouville equation.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Research groups

Groupe Bill

Citation (ISO format)

BILL, Hans. An O^-₂ molecule ion in CaF₂: Structure and dynamical features. In: The Journal of chemical physics, 1979, vol. 70, n° 1, p. 277–283. doi: 10.1063/1.437243

Article (Published version)

Identifiers

PID : unige:3132
DOI : 10.1063/1.437243

Journal ISSN0021-9606

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An O-2 molecule ion in CaF2: Structure and dynamical features

Technical informations

An O^-₂ molecule ion in CaF₂: Structure and dynamical features