Analogs of the Rose center in the alkaline earth fluorides: Production by hydrolysis and identification by Raman spectroscopy

Deyhimi, Farzad; Bill, Hans

doi:10.1016/0022-4596(82)90227-4

Scientific article

English

Analogs of the Rose center in the alkaline earth fluorides: Production by hydrolysis and identification by Raman spectroscopy

ContributorsDeyhimi, Farzad; Bill, Hans

Published inJournal of solid state chemistry, vol. 43, no. 2, p. 181-189

Publication date1982

Abstract

A family of molecular centers of the type (RO₂M)²⁺ is shown to exist in the alkaline earth fluorides MF₂ (M = Ca, Sr, Ba) doped with R = Sc, Y, Lu, Ho when these crystals have been hydrolyzed and subsequently X-rayed. The centers were identified with the aid of Raman spectroscopy and, in the past, with electron paramagnetic resonance (EPR).

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Research groups

Groupe Bill

Citation (ISO format)

DEYHIMI, Farzad, BILL, Hans. Analogs of the Rose center in the alkaline earth fluorides: Production by hydrolysis and identification by Raman spectroscopy. In: Journal of solid state chemistry, 1982, vol. 43, n° 2, p. 181–189. doi: 10.1016/0022-4596(82)90227-4

Article (Published version)

Identifiers

PID : unige:3116
DOI : 10.1016/0022-4596(82)90227-4

Journal ISSN0022-4596

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Analogs of the Rose center in the alkaline earth fluorides: Production by hydrolysis and identification by Raman spectroscopy

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