Scientific article
English

(ReO4)2- ion in KCI: Experimental evidence for a multimode intramolecular Jahn-Teller effect

Published inPhysical review. B, Condensed matter and materials physics, vol. 28, no. 5, p. 2352-2355
Publication date1983-09-01
Abstract

For the first time, experimental results have been obtained on a transition-metal tetroxy anion stabilized without any associated defects in a cubic crystal: the (ReO4)2- ion in KCI. Our EPR study, including experiments under uniaxial stress and static electric fields applied to the crystal, shows that a strong and essentially intramolecular Jahn-Teller effect occurs but not exclusively of the E⊗ε type. Appropriate linear combinations of the T2 vibrations involving a pseudo-Jahn-Teller effect and spin-orbit coupling must play an important part.

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Citation (ISO format)
BILL, Hans, RAVI SEKHAR, Y. (ReO4)2- ion in KCI: Experimental evidence for a multimode intramolecular Jahn-Teller effect. In: Physical review. B, Condensed matter and materials physics, 1983, vol. 28, n° 5, p. 2352–2355. doi: 10.1103/PhysRevB.28.2352
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Additional URL for this publicationhttp://prola.aps.org/pdf/PRB/v28/i5/p2352_1
Journal ISSN1098-0121
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