The identification and structure of FSO2 radical trapped in potassium sulphate crystals

Ravi Sekhar, Y.; Bill, Hans; Lovy, Dominique

doi:10.1016/0009-2614(87)87298-6

Scientific article

English

The identification and structure of FSO2 radical trapped in potassium sulphate crystals

ContributorsRavi Sekhar, Y.; Bill, Hans; Lovy, Dominique

Published inChemical physics letters, vol. 136, no. 1, p. 57-61

Publication date1987

Abstract

ESR and ENDOR results on irradiated K2SO4:BF4− crystals are presented. Based on the ESR spectra and their symmetry at the X and Ka bands, a new paramagnetic radical trapped at the sulphate sites is identified. The ENDOR spectra are consistent with the involvement of a fluorine nucleus. The spectra are assigned to the symmetric FSO2 radical.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Research groups

Groupe Bill

Citation (ISO format)

RAVI SEKHAR, Y., BILL, Hans, LOVY, Dominique. The identification and structure of FSO2 radical trapped in potassium sulphate crystals. In: Chemical physics letters, 1987, vol. 136, n° 1, p. 57–61. doi: 10.1016/0009-2614(87)87298-6

Identifiers

PID : unige:3091
DOI : 10.1016/0009-2614(87)87298-6

Journal ISSN0009-2614

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The identification and structure of FSO2 radical trapped in potassium sulphate crystals

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