Theoretical and ESR/ENDOR single-crystal study of an azaallyl radical

Reddy, Malledi V. V. S.; Celalyan-Berthier, Alice; Geoffroy, Michel; Morgantini, Pierre-Yves; Weber, Jacques; Bernardinelli, Gérald Hugues

doi:10.1021/ja00217a009

Scientific article

English

Theoretical and ESR/ENDOR single-crystal study of an azaallyl radical

ContributorsReddy, Malledi V. V. S.; Celalyan-Berthier, Alice; Geoffroy, Michel; Morgantini, Pierre-Yves; Weber, Jacques; Bernardinelli, Gérald Hugues

Published inJournal of the American Chemical Society, vol. 110, no. 9, p. 2748-2753

Publication date1988

Abstract

The room-temperature-stable radical trapped in an X-irradiated single crystal of 2-bromo-5-nitrothiazole has been studied by 'H ENDOR and by ESR. The structure of the undamaged crystal has been determined. The g tensor, the magnetic hyperfine tensors with IH, 79Br, 'Br, and the quadrupolar interaction tensors with 79Br and 'Br have been obtained and their orientations are

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

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Citation (ISO format)

REDDY, Malledi V. V. S. et al. Theoretical and ESR/ENDOR single-crystal study of an azaallyl radical. In: Journal of the American Chemical Society, 1988, vol. 110, n° 9, p. 2748–2753. doi: 10.1021/ja00217a009

Identifiers

PID : unige:3078
DOI : 10.1021/ja00217a009

ISSN of the journal0002-7863

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Theoretical and ESR/ENDOR single-crystal study of an azaallyl radical

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