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Silver impurities in cubic metal fluorides : Jahn-Teller effects in the 4d95s1 and 4d9 multiplets

Publication date1995
Abstract

Silver was introduced into several metal fluorides with the aim to generate different Jahn-Teller (JT) situations. Optical absorption and luminescence experiments involving the ground 4d10 апd the excited 4d95s1 configuration of Ag+ revealed a weak T ⊗ e JT effect in the (approximately) T2 excited triplets in NaF and SrF2, but much stronger differences between different hosts in the (approx.) E doublet. The strongest effect was observed in the host NaF. The theoretical developments initiated by Wagner have given the best interpretation of the observed temperature dependence of optical line shapes. EPR experiments (in part with a sample under uniaxial stress) on Ag2+ in MeF2 crystals (Me: Ca, Sr, Ba) and SrCl2 demonstrated the action of a T2 ⊗ t2 JT effect for the former two hosts and, probably, a quadratic JT effect or an off-centre situation for the latter two. The experimental results and models are presented.

Keywords
  • Impurity centres
  • Triplet Jahn-Teller effect
  • Jahn-Teller-induced relaxation
  • Jahn- Teller effect in excited states
  • Fluoride hosts (cubic)
Research groups
Citation (ISO format)
BOUTINAUD, Philippe et al. Silver impurities in cubic metal fluorides : Jahn-Teller effects in the 4d95s1 and 4d9 multiplets. In: Proceedings of the Estonian Academy of Sciences. Physics. Mathematics, 1995, vol. 44, n° 2/3, p. 199–204. doi: 10.3176/phys.math.1995.2/3.09
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Article (Published version)
accessLevelPublic
Identifiers
Journal ISSN1406-0086
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