Synthesis, structure and ligand-centred reduction of an orthometallated complex of palladium containing two phosphaalkene groups

Jouaiti, Abdelaziz; Geoffroy, Michel; Terron, Gustavo; Bernardinelli, Gérald Hugues

doi:10.1039/C39920000155

Article scientifique

Anglais

Synthesis, structure and ligand-centred reduction of an orthometallated complex of palladium containing two phosphaalkene groups

Contributeurs/tricesJouaiti, Abdelaziz; Geoffroy, Michel; Terron, Gustavo; Bernardinelli, Gérald Hugues

Publié dansJournal of the Chemical Society. Chemical communications, no. 2, p. 155-156

Date de publication1992

Résumé

A novel ligand containing two phosphaalkene moieties has been synthesized, which forms a palladium(II) complex whose crystal structure has been determined and whose reduction has been shown, by EPR spectroscopy, to take place on the ligand rather than on the metal.

Structure d'affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Groupe de recherche

Groupe Geoffroy

Citation (format ISO)

JOUAITI, Abdelaziz et al. Synthesis, structure and ligand-centred reduction of an orthometallated complex of palladium containing two phosphaalkene groups. In: Journal of the Chemical Society. Chemical communications, 1992, n° 2, p. 155–156. doi: 10.1039/C39920000155

Article (Published version)

Identifiants

PID : unige:2917
DOI : 10.1039/C39920000155

ISSN du journal0022-4936

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Synthesis, structure and ligand-centred reduction of an orthometallated complex of palladium containing two phosphaalkene groups

A novel ligand containing two phosphaalkene moieties has been synthesized, which forms a palladium(II) complex whose crystal structure has been determined and whose reduction has been shown, by EPR spectroscopy, to take place on the ligand rather than on the metal.

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