Modular Asymmetric Synthesis of Pochonin C

Barluenga, Sofia; Lopez, Pilar; Moulin, Emilie; Winssinger, Nicolas

doi:10.1002/anie.200454108

Scientific article

English

Modular Asymmetric Synthesis of Pochonin C

ContributorsBarluenga, Sofia; Lopez, Pilar; Moulin, Emilie; Winssinger, Nicolas

Published inAngewandte Chemie, vol. 43, no. 26, p. 3467-3470

Publication date2004

Abstract

Back to its origins: Pochonin C was synthesized in 11 steps from the four fragments shown in the scheme. This asymmetric synthesis and the conversion of pochonin C into radicicol defines the configuration at the center bearing the chlorine atom as S. Ipc=isopenocampheyl, PG=protecting group.

Keywords

asymmetric synthesis
conformation analysis
metathesis
natural products
total synthesis

Affiliation entities

Not a UNIGE publication

Citation (ISO format)

BARLUENGA, Sofia et al. Modular Asymmetric Synthesis of Pochonin C. In: Angewandte Chemie, 2004, vol. 43, n° 26, p. 3467–3470. doi: 10.1002/anie.200454108

Article (Published version)

Identifiers

PID : unige:24742
DOI : 10.1002/anie.200454108

Journal ISSN1433-7851

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Creation11/12/2012 16:43:00

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Update time14/03/2023 17:47:59

Status update14/03/2023 17:47:59

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Modular Asymmetric Synthesis of Pochonin C

Back to its origins: Pochonin C was synthesized in 11 steps from the four fragments shown in the scheme. This asymmetric synthesis and the conversion of pochonin C into radicicol defines the configuration at the center bearing the chlorine atom as S. Ipc=isopenocampheyl, PG=protecting group.

Technical informations