Chromium(III)-trisoxalate, a versatile building block for luminescent materials

Milos, Mia; Hauser, Andreas

doi:10.1016/j.jlumin.2011.12.053

Scientific article

English

Chromium(III)-trisoxalate, a versatile building block for luminescent materials

ContributorsMilos, Mia; Hauser, Andreas

Published inJournal of luminescence, vol. 133, p. 15-20

Publication date2013

Abstract

Chromium(III)-trisoxalate,[Cr(ox)3]3- (ox = C2O42-), incorporated into polymeric networks of composition [NaCr(ox)3][MII(bpy)3] and [NaCr(ox)3][MIII(bpy)3]ClO4 (bpy= 2,2'-bipyridine, MII = Zn, Fe, Ru; MIII = Rh, Cr), results in interesting features ranging from phonon-assisted and resonant energy migration within the R1 line the 2E state to persistent spectral side-hole burning via the latter, and manifestations of specific nearest-neighbour π–π interactions between bipyridine and oxalate.

Keywords

Chromium(III)-tris-oxalate
Energy migration
Fluorescence line narrowing
Spectral diffusion
Persistent spectral hole burning

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Research group

Groupe Hauser

Citation (ISO format)

MILOS, Mia, HAUSER, Andreas. Chromium(III)-trisoxalate, a versatile building block for luminescent materials. In: Journal of luminescence, 2013, vol. 133, p. 15–20. doi: 10.1016/j.jlumin.2011.12.053

Article (Published version)

Identifiers

PID : unige:24060
DOI : 10.1016/j.jlumin.2011.12.053

Commercial URLhttp://linkinghub.elsevier.com/retrieve/pii/S0022231311007228

ISSN of the journal0022-2313

621views

0downloads

Creation11/16/2012 1:57:00 PM

First validation11/16/2012 1:57:00 PM

Update time03/14/2023 5:45:16 PM

Status update03/14/2023 5:45:16 PM

Last indexation01/16/2024 12:31:53 AM

Archive ouverte UNIGE

Chromium(III)-trisoxalate, a versatile building block for luminescent materials

Technical informations