Scientific article
English

The kinetics features of a thermal spin transition characterized by optical microscopy on the example of [Fe(bbtr)3](ClO4)2 single crystals: Size effect and mechanical instability

Published inChemical physics letters, vol. 504, no. 1-3, p. 29-33
Publication date2011
Abstract

We investigated by optical microscopy the thermal spin transition in single crystals of [Fe(bbtr)3](ClO4)2 (bbtr = 1,4-di(1,2,3-triazol-1-yl) butane). The growth of the low-spin phase was observed for different crystal orientations and sizes. The process always started from a corner of the crystal but its further development depended on the size, shape and thermal history of the crystal. In crystals of smaller size, under isothermal conditions, the low-spin phase developed in a continuous way, through the propagation of a rather well defined transformation front, with a higher propagation velocity inside the planes perpendicular to the c axis. In larger crystals the spontaneous occurrence of inhomogeneous stresses led to a stepwise propagation process.

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Citation (ISO format)
CHONG, Christian et al. The kinetics features of a thermal spin transition characterized by optical microscopy on the example of [Fe(bbtr)3](ClO4)2 single crystals: Size effect and mechanical instability. In: Chemical physics letters, 2011, vol. 504, n° 1-3, p. 29–33. doi: 10.1016/j.cplett.2011.01.041
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Journal ISSN0009-2614
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Creation29/08/2011 07:59:00
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