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Title

One-Step Catalytic Asymmetric Synthesis of Configurationally Stable Tröger Bases

Authors
Naubron, Jean-Valère
Published in Angewandte Chemie: International Edition. 2011, vol. 50, no. 16, p. 3677 - 3680
Abstract Bridging the gap: Configurationally stable ethano-bridged Tröger bases have been prepared in a single step by the direct rhodium(II)-catalyzed reaction of methano-bridged Tröger bases and diazo esters (see scheme). The process is general, enantiospecific, diastereoselective (with introduction of a new quaternary carbon center), and regioselective.
Keywords CarbenoidsDiazo compoundsRearrangementRhodiumTröger bases
Stable URL http://archive-ouverte.unige.ch/unige:14935
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Other version: http://doi.wiley.com/10.1002/anie.201100134
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Deposited on : 2011-04-11

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