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Accurate intermolecular binding energies of 1-naphthol to benzene and cyclohexane
|Published in||Chemical Physics Letters. 1997, vol. 264, no. 3-4, p. 257-264|
|Abstract||Accurate dissociation energies were determined for gas-phase complexes between 1-naphthol and benzene, d6-benzene and cyclohexane, using the stimulated emission pumping resonant two-photon ionization spectroscopy technique in supersonic jets. The dissociation energies obtained for the electronic ground state are surprisingly large being D0 = 5.07±0.07 kcal/mol for 1-naphthol · benzene, 5.08±0.06 kcal/mol for 1-naphthol · d6-benzene, and 6.92±0.03 kcal/mol for 1-naphthol · cyclohexane, respectively. The dissociation energies scale well with the parallel molecular polarizabilities.|