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CpRu-Catalyzed O−H Insertion and Condensation Reactions of α-Diazocarbonyl Compounds

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Published in Organic Letters. 2011, vol. 13, no. 6, p. 1394-1397
Abstract [CpRu(CH3CN)3][PF6] and diimine ligands catalyze together the decomposition of α-diazocarbonyl compounds leading to O−H insertion and condensation reactions. In comparison with Rh(II) and Cu(I) complexes, the CpRu catalysts produce rapid and often more selective reactions. Promising enantioselectivities are obtained in dioxole syntheses.
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Other version: http://pubs.acs.org/doi/abs/10.1021/ol2000815
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Deposited on : 2011-03-11

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