CpRu-Catalyzed O−H Insertion and Condensation Reactions of α-Diazocarbonyl Compounds

Austeri, Martina; Rix, Diane; Zeghida, Walid; Lacour, Jérôme

doi:10.1021/ol2000815

Scientific article

English

CpRu-Catalyzed O−H Insertion and Condensation Reactions of α-Diazocarbonyl Compounds

ContributorsAusteri, Martina; Rix, Diane; Zeghida, Walid; Lacour, Jérôme

Published inOrganic letters, vol. 13, no. 6, p. 1394-1397

Publication date2011

Abstract

[CpRu(CH3CN)3][PF6] and diimine ligands catalyze together the decomposition of α-diazocarbonyl compounds leading to O−H insertion and condensation reactions. In comparison with Rh(II) and Cu(I) complexes, the CpRu catalysts produce rapid and often more selective reactions. Promising enantioselectivities are obtained in dioxole syntheses.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

AUSTERI, Martina et al. CpRu-Catalyzed O−H Insertion and Condensation Reactions of α-Diazocarbonyl Compounds. In: Organic letters, 2011, vol. 13, n° 6, p. 1394–1397. doi: 10.1021/ol2000815

Article (Published version)

Identifiers

PID : unige:14595
DOI : 10.1021/ol2000815

Journal ISSN1523-7052

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Creation11/03/2011 15:32:00

First validation11/03/2011 15:32:00

Update time14/03/2023 16:13:27

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CpRu-Catalyzed O−H Insertion and Condensation Reactions of α-Diazocarbonyl Compounds

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