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Title

Chiral Ruthenium Lewis Acid Catalyzed Intramolecular Diels−Alder Reactions

Authors
Besnard, Céline
Published in Organic Letters. 2010, vol. 12, no. 24, p. 5604 - 5607
Abstract Single point binding ruthenium Lewis acid catalysts [Ru(acetone)(S,S)-BIPHOP-F)Cp][SbF6] ((S,S)-1b) and [Ru(acetone)(S,S)-BIPHOP-F)(indenyl)][SbF6] ((S,S)-1c) efficiently catalyze intramolecular Diels−Alder (IMDA) reactions under mild conditions to afford the endo cycloaddition products as the major product in excellent yields with high diastereo- and enantioselectivities.
Stable URL http://archive-ouverte.unige.ch/unige:12856
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Other version: http://pubs.acs.org/doi/abs/10.1021/ol1019103
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Deposited on : 2010-12-13

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