Construction of enantioenriched cyclic compounds via asymmetric allylic alkylation and ring closing metathesis

Giacomina, Francesca

doi:10.13097/archive-ouverte/unige:12234

Doctoral thesis

English

Construction of enantioenriched cyclic compounds via asymmetric allylic alkylation and ring closing metathesis

ContributorsGiacomina, Francesca

DirectorsAlexakis, Alexandre

Defense date2010-09-30

Abstract

A new strategy to access highly enantioenriched cyclic compounds was studied using ω-ethylenic allylic substrates through a one-pot asymmetric allylic alkylation and ring-closing metathesis. Such starting compounds can be seen as synthetic equivalents of cyclic allylic substrates.

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

GIACOMINA, Francesca. Construction of enantioenriched cyclic compounds via asymmetric allylic alkylation and ring closing metathesis. 2010. doi: 10.13097/archive-ouverte/unige:12234

Thesis

Identifiers

PID : unige:12234
DOI : 10.13097/archive-ouverte/unige:12234
URN : urn:nbn:ch:unige-122346
Thesis number : Sc. 4255

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Creation10/21/2010 10:48:00 PM

First validation10/21/2010 10:48:00 PM

Update time03/14/2023 4:08:00 PM

Status update03/14/2023 4:08:00 PM

Last indexation01/29/2024 7:02:41 PM

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Construction of enantioenriched cyclic compounds via asymmetric allylic alkylation and ring closing metathesis

A new strategy to access highly enantioenriched cyclic compounds was studied using ω-ethylenic allylic substrates through a one-pot asymmetric allylic alkylation and ring-closing metathesis. Such starting compounds can be seen as synthetic equivalents of cyclic allylic substrates.

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