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Title

A Chiral and Colorful Redox Switch: Enhanced π Acidity in Action

Authors
Vargas Jentzsch, Andreas
Sakurai, Shin-ichiro
Published in Angewandte Chemie: International Edition. 2010, vol. 49, no. 42, p. 7680 - 7683
Abstract Deep blue diving: π Acidities up to a new record of −4.74 eV are made possible with simple sulfur redox chemistry (see scheme). This attractive method is able to generate exceptional electron affinities and anion transport efficiencies for applications in optoelectronic devices, medicinal chemistry, and anion–π catalysis.
Keywords Anion–π interactionsChiralityIon transportMolecular switchesπ acidity
Stable URL http://archive-ouverte.unige.ch/unige:12065
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Other version: http://doi.wiley.com/10.1002/anie.201003722
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Deposited on : 2010-10-11

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