UNIGE document Scientific Article
previous document  unige:11858  next document
add to browser collection

Chiral hexacoordinated phosphates: From pioneering studies to modern uses in stereochemistry

Published in Comptes rendus chimie. 2010, vol. 13, no. 8-9, p. 985-997
Abstract Chiral cationic molecular structures and supramolecular assemblies can be effectively analyzed, resolved and stereocontrolled through an asymmetric ion pairing with enantiopure hexacoordinated phosphate anions like TRISPHAT or BINPHAT. After an historical perspective on the development of these anionic reagents, this account describes their synthesis and their use as chiral NMR solvating, resolving and asymmetry-inducing reagents.
Keywords Hexacoordinated phosphorusAsymmetric ion pairingChiral anionNMR enantiodifferentiationResolutionSupramolecular stereocontrol
Stable URL http://archive-ouverte.unige.ch/unige:11858
Full text
158 hits and 1 download since 2010-09-17
Export document
Format :
Citation style :