Chiral hexacoordinated phosphates: From pioneering studies to modern uses in stereochemistry

Lacour, Jérôme

doi:10.1016/j.crci.2010.02.009

Scientific article

English

Chiral hexacoordinated phosphates: From pioneering studies to modern uses in stereochemistry

ContributorsLacour, Jérôme

Published inComptes rendus. Chimie, vol. 13, no. 8-9, p. 985-997

Publication date2010

Abstract

Chiral cationic molecular structures and supramolecular assemblies can be effectively analyzed, resolved and stereocontrolled through an asymmetric ion pairing with enantiopure hexacoordinated phosphate anions like TRISPHAT or BINPHAT. After an historical perspective on the development of these anionic reagents, this account describes their synthesis and their use as chiral NMR solvating, resolving and asymmetry-inducing reagents.

Keywords

Hexacoordinated phosphorus
Asymmetric ion pairing
Chiral anion
NMR enantiodifferentiation
Resolution
Supramolecular stereocontrol

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

LACOUR, Jérôme. Chiral hexacoordinated phosphates: From pioneering studies to modern uses in stereochemistry. In: Comptes rendus. Chimie, 2010, vol. 13, n° 8-9, p. 985–997. doi: 10.1016/j.crci.2010.02.009

Article (Published version)

Identifiers

PID : unige:11858
DOI : 10.1016/j.crci.2010.02.009

Additional URL for this publicationhttp://linkinghub.elsevier.com/retrieve/pii/S1631074810000391

Journal ISSN1631-0748

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Chiral hexacoordinated phosphates: From pioneering studies to modern uses in stereochemistry

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