Département de chimie organique

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2016

Scientific Articles

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A novel HSP90 inhibitor with reduced hepatotoxicity synergizes with radiotherapy to induce apoptosis, abrogate clonogenic survival, and improve tumor control in models of colorectal cancerKinzel, Linda; Ernst, Anne; Orth, Michael; Albrecht, Valerie; ... Lauber, Kirsten
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A ratiometric luminescent switch based on platinum complexes tethered to a crown-ether scaffoldSinn, Stephan; Biedermann, Frank; Vishe, Mahesh; Aliprandi, Alessandro; ... De Cola, Luisa
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Activation of Cell-Penetrating Peptides with Ionpair−π Interactions and FluorophilesChuard, Nicolas; Fujisawa, Kaori; Morelli, Paola; Saarbach, Jacques; ... Matile, Stefan
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Allosterically Regulated Phosphatase Activity from Peptide-PNA Conjugates Folded Through HybridizationMachida, Takuya; Dutt, Som; Winssinger, Nicolas;
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Anion Transport with Chalcogen BondsBenz, Sebastian; Macchione, Mariano; Verolet, Quentin; Mareda, Jiri; ... Matile, Stefan
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Anion-π Catalysis of Enolate Chemistry: Rigidified Leonard Turns as a General Motif to Run Reactions on Aromatic SurfacesCotelle, Yoann; Benz, Sebastian; Avestro, Alyssa-Jennifer; Ward, Thomas R.; ... Matile, Stefan
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Anion-π EnzymesCotelle, Yoann; Lebrun, Vincent; Sakai, Naomi; Ward, Thomas R.; Matile, Stefan
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Asymmetric Anion-π Catalysis on PerylenediimidesWang, Chao; Miros, François; Mareda, Jiri; Sakai, Naomi; Matile, Stefan
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Asymmetric Anion−π Catalysis of Iminium/Nitroaldol Cascades To Form Cyclohexane Rings with Five Stereogenic Centers Directly on π-Acidic SurfacesLiu, Le; Cotelle, Yoann; Avestro, Alyssa-Jennifer; Sakai, Naomi; Matile, Stefan
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Catalytic Enantioselective Total Synthesis of Riccardiphenol BCottet, Pierre; Bleschke, Christian Alexander; Guiteras Capdevila, Montserrat; Tissot, Matthieu; Alexakis, Alexandre
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Characterization of Dimethylsulfoxide / Glycerol Mixtures: A Binary Solvent System for the Study of "Friction-Dependent" Chemical ReactivityAngulo Nunez, Gonzalo Manuel; Brucka, Anna; Gerecke, Mario; Grampp, Günter; ... Wnuk, Paweł
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Chemoproteomics-Enabled Discovery of a Potent and Selective Inhibitor of the DNA Repair Protein MGMTWang, Chao; Abegg, Daniel; Hoch, Dominic Gregor; Adibekian, Alexander;
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Computational Study on the Mechanism of the Palladium-Catalyzed Arylation of α,β-Unsaturated AldehydesFranzoni, Ivan; Poblador Bahamonde, Amalia Isabel;
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Configurationally Stable Doubly Bridged Biphenyl Azocines through Copper-Catalyzed Double Carbene Insertions into the Corresponding AzepinesHarthong, Steven; Brun, Elodie; Grass, Stéphane; Besnard, Céline; ... Lacour, Jérôme
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Copper-Catalyzed Enantioselective Conjugate Addition to α,β-Unsaturated Aldehydes with Various Organometallic ReagentsContal, Sylvie; Gremaud, Ludovic; Palais, Laetitia; Babel, Lucille; Alexakis, Alexandre
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Core-Substituted Naphthalenediimides: LUMO Levels Revisited, in Comparison with Preylenediimides with Sulfur Redox Switches in the CoreMiros, François; Matile, Stefan;
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Cutting Edge Chemical Biology: Report from the 2016 International Symposium on Chemical Biology, January 13–15, Geneva, SwitzerlandAdibekian, Alexander; Stallforth, Pierre;
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Dipolar Photosystems: Engineering Oriented Push-Pull Components into Double- and Triple-Channel Surface ArchitecturesBolag, Alatengbaolige; Sakai, Naomi; Matile, Stefan;
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Direct Access to Furoindolines by Palladium-Catalyzed Intermolecular CarboaminationBizet, Vincent; Borrajo Calleja, Gustavo; Besnard, Céline; Mazet, Clement;
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Direct Organocatalysed Double Michael Addition of α-Angelica Lactone to EnonesLagoutte, Roman; Besnard, Céline; Alexakis, Alexandre;
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Discrimination of hexabromocyclododecane from new polymeric brominated flame retardant in polystyrene foam by nuclear magnetic resonanceJeannerat, Damien; Pupier, Marion; Schweizer, Sébastien; Mitrev, Yavor Nikolaev; ... Kohler, Marcel
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Divergent synthesis and identification of the cellular targets of deoxyelephantopinsLagoutte, Roman; Serba, Christelle; Abegg, Daniel; Hoch, Dominic Gregor; ... Winssinger, Nicolas
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Duplex formation and secondary structure of γ-PNA observed by NMR and CDViéville, J.M.P.; Barluenga Badiola, Sofia; Winssinger, Nicolas; Delsuc, M.A.;
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Engineering Protein Self-Assembly: A New Approach for the Design of Octahedral CagesCougnon, Fabien;
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Ethynyl benziodoxolones: functional terminators for cell-penetrating poly(disulfide)sMorelli, Paola; Martin Benlloch, Xavier; Tessier, Romain; Waser, Jérôme; ... Matile, Stefan
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Expanded Chiral Surfaces for Asymmetric Anion–π CatalysisAkamatsu, Masaaki; Matile, Stefan;
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Functionalized cationic [4]helicenes with unique tuning of absorption, fluorescence and chiroptical properties up to the far-red rangeHernandez Delgado, Irene; Pascal, Simon; Wallabregue, Antoine; Duwald, Romain; ... Lacour, Jérôme
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Headgroup engineering in mechanosensitive membrane probesSoleimanpour, Saeideh; Colom Diego, Adai; Derivery, Emmanuel; Gonzalez Gaitan, Marcos; ... Matile, Stefan
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Helicenes : A New Class of Organic Spin FilterKiran, Vankayala; Mathew, Shinto P.; Cohen, Sidney R.; Hernandez Delgado, Irene; ... Naaman, Ron
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High Spatial Resolution Imaging of Endogenous Hydrogen Peroxide in Living Cells by Solid-State FluorescenceLindberg, Eric; Winssinger, Nicolas;
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High-Performance Liquid Chromatographic Resolution of Neutral and Cationic Hetero[6]HelicenesLabrador Beltran, Maria Géraldine; Bosson, Johann; Breitbach, Zachary S.; Lim, Yeeun; ... Lacour, Jérôme
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Interfacing Functional SystemsCotelle, Yoann; Chuard, Nicolas; Lascano, Santiago; Lebrun, Vincent; ... Matile, Stefan
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Iridium-Catalyzed Selective Isomerization of Primary Allylic AlcoholsLi, Houhua; Mazet, Clement;
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Kinetics of Rh(II)-Catalyzed α-Diazo-β-ketoester Decomposition and Application to the [3+6+3+6] Synthesis of Macrocycles on Large Scale and Low Catalyst LoadingsPoggiali, Daniele; Homberg, Alexandre; Lathion, Timothee; Piguet, Claude; Lacour, Jérôme
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New biphenyl iminium salt catalysts for highly enantioselective asymmetric epoxidation: role of additional substitution and dihedral angleBulman Page, Philip C.; Bartlett, Christopher J.; Chan, Yohan; Allin, Steven M.; ... Jones, Garth A.
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NMR analysis of weak molecular interactions using slice-selective experiments via study of concentration gradients in agar gelsMitrev, Yavor Nikolaev; Simova, Svetlana; Jeannerat, Damien;
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Novel PTP1B inhibitors identified by DNA display of fragment pairsBarluenga Badiola, Sofia; Zambaldo, Claudio; Ioannidou, Heraklidia A.; Ciobanu, Mihai; ... Winssinger, Nicolas
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Nucleic Acid Templated Chemical Reaction in a Live VertebrateHoltzer, Laurentius Henricus; Oleinich, Igor; Anzola, Marcello; Lindberg, Eric; ... Winssinger, Nicolas
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One-Step Derivatization of Reducing Oligosaccharides for Rapid and Live-Cell Compatible Chelation-Assisted CuAAC ConjugationMachida, Takuya; Winssinger, Nicolas;
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Palladium-Catalyzed Enantioselective Intermolecular Carboetherification of DihydrofuransBorrajo Calleja, Gustavo; Bizet, Vincent; Mazet, Clement;
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Palladium-Catalyzed Long-Range Deconjugative Isomerization of Highly Substituted α,β-Unsaturated Carbonyl CompoundsLin, Luqing; Romano, Ciro; Mazet, Clement;
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Physicochemical and Electronic Properties of Cationic [6]Helicenes: from Chemical and Electrochemical Stabilities to Far-Red (Polarized) LuminescenceBosson, Johann; Labrador Beltran, Maria Géraldine; Pascal, Simon; Miannay, François-Alexandre; ... Lacour, Jérôme
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Potassium ion-selective fluorescent and pH independent nanosensors based on functionalized polyether macrocyclesJarolimova, Zdenka; Vishe, Mahesh; Lacour, Jérôme; Bakker, Eric;
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Rapid and Scalable Synthesis of cis-Fused Guaiane-Type SesquiterpenesSerba, Christelle; Lagoutte, Roman; Winssinger, Nicolas;
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Regioselective Synthesis and Characterization of Multinuclear Convex-Bound Ruthenium-[n]Cycloparaphenylene (n]Cycloparaphenylene (n=5 and 6) ComplexesKayahara, Eiichi; Patel, Vijay Kumar; Mercier, Audrey Catherine Marie; Kundig, Ernst Peter; Yamago, Shigeru
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Ruthenium Lewis Acid-Catalyzed Asymmetric Diels-Alder Reactions: Reverse-Face Selectivity for α,β-Unsaturated Aldehydes and KetonesThamapipol, Sirinporn; Ludwig, Bettina; Besnard, Céline; Saudan, Christophe; Kundig, Ernst Peter
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Screening for covalent inhibitors using DNA-display of small molecule libraries functionalized with cysteine reactive moietiesZambaldo, Claudio; Daguer, Jean Pierre; Saarbach, Jacques; Barluenga Badiola, Sofia; Winssinger, Nicolas
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Selective Imaging of Late Endosomes with a pH-Sensitive Diazaoxatriangulene Fluorescent ProbeWallabregue, Antoine; Moreau, Dimitri; Sherin, Petr; Moneva Lorente, Pau; ... Lacour, Jérôme
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Surveying the Delivery Methods of CRISPR/Cas9 for ex vivo Mammalian Cell EngineeringKelton, William J.; Pesch, Theresa; Matile, Stefan; Reddy, Sai T.;
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Synthesis of Pyrrolidines and Pyrrolizidines with α-Pseudoquaternary Centers by Copper-Catalyzed Condensation of α-Diazodicarbonyl Compounds and Aryl γ-LactamsGoudedranche, Sébastien; Besnard, Céline; Egger, Leo; Lacour, Jérôme;
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Synthesis of Spiro Ketals, Orthoesters, and Orthocarbonates by CpRu-Catalyzed Decomposition of α-Diazo-β-ketoestersTortoreto, Cecilia; Achard, Thierry; Egger, Leo; Guenee, Laure; Lacour, Jérôme
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The diastereoselective synthesis of octahedral cationic iridium hydride complexes with a stereogenic metal centreHumbert, Nicolas; Mazet, Clement;
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The third orthogonal dynamic covalent bondLascano, Santiago; Zhang, Kangda; Wehlauch, Robin; Gademann, Karl; ... Matile, Stefan
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Unorthodox Interactions at WorkZhao, Yingjie; Cotelle, Yoann; Sakai, Naomi; Matile, Stefan;
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Zwitterionic [4]helicene: a water-soluble and reversible pH-triggered ECD/CPL chiroptical switch in the UV and red spectral regionsPascal, Simon; Besnard, Céline; Zinna, Francesco; Di Bari, Lorenzo; ... Lacour, Jérôme

Book Chapters

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Functionalization of Arenes via C ─H Bond Activation Catalysed by Transition Metal Complexes: Synergy between Experiment and TheoryPoblador Bahamonde, Amalia Isabel;
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Organometallic Complexes of IridiumLi, Houhua; Mazet, Clement; Aitken, R. Alan; Nielsen, Mogens Brønsted; ... Wirth, Thomas

Doctoral Thesis

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Complex surface architectures: the discovery of the third orthogonal dynamic covalent bondLascano, Santiago;
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Mechanistic investigations and development of Rh(II)-catalyzed [3+6+3+6] macrocyclization reactionsPoggiali, Daniele;

2015

Scientific Articles

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1D NMR Homodecoupled 1H Spectra with Scalar Coupling Constants from 2D NemoZS-DIAG ExperimentsCotte, Axelle; Jeannerat, Damien;
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A general Pd-catalyzed α- and γ-benzylation of aldehydes for the formation of quaternary centersFranzoni, Ivan; Guenee, Laure; Mazet, Clement;
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A Mild and Efficient CH2-Extrusion Reaction for the Enantiospecific Synthesis of Highly Configurationally Stable Tröger BasesPujari, Sandip A.; Besnard, Céline; Buergi, Thomas; Lacour, Jérôme;
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Access to enantioenriched 2,3- and 2,5-dihydrofurans with a fully substituted C2 stereocenter by Pd-catalyzed asymmetric intermolecular Heck reactionBorrajo Calleja, Gustavo; Bizet, Vincent; Buergi, Thomas; Mazet, Clement;
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Asymmetric Anion-π Catalysis: Enamine Addition to Nitroolefins on π-Acidic SurfacesZhao, Yingjie; Cotelle, Yoann; Avestro, Alyssa-Jennifer; Sakai, Naomi; Matile, Stefan
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Asymmetric Bromine-Lithium Exchange: Application toward the Synthesis of New Biaryl-Diphosphine LigandsGraff, Julien; Lastawiecka, Elzbieta; Guenee, Laure; Leroux, Frederick; Alexakis, Alexandre
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Asymmetric bromine–lithium exchange: on the importance of both the diamine ligand and the organolithium reagentPraz, Jezabel; Graff, Julien; Egger, Leo; Guenee, Laure; ... Alexakis, Alexandre
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Big, Strong, Neutral, Twisted, and Chiral π AcidsZhao, Yingjie; Huang, Guangxi; Besnard, Céline; Mareda, Jiri; ... Matile, Stefan
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Catalyst-Directed Diastereoselective Isomerization of Allylic Alcohols for the Stereoselective Construction of C(20) in Steroid Side Chains: Scope and Topological DiversificationLi, Houhua; Mazet, Clement;
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Cell-penetrating poly(disulfide)s: the dependence of activity, depolymerization kinetics and intracellular localization on their lengthChuard, Nicolas; Gasparini, Giulio; Roux, Aurélien; Sakai, Naomi; Matile, Stefan
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Cellular uptake: lessons from supramolecular organic chemistryGasparini, Giulio; Bang, Eun Kyoung; Montenegro Garcia, Javier; Matile, Stefan;
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ChemInform Abstract: A Mild and Efficient CH2-Extrusion Reaction for the Enantiospecific Synthesis of Highly Configurationally Stable Troeger BasesPujari, Sandip; Besnard, Celine; Buergi, Thomas; Lacour, Jerome;
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Colorful surface architectures with three different types of dynamic covalent bonds: integration of anthocyanins, tritylium ions and flavinsZhang, Kangda; Sakai, Naomi; Matile, Stefan;
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Complex Functional Systems with Three Different Types of Dynamic Covalent BondsZhang, Kangda; Matile, Stefan;
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Copper-Catalyzed Asymmetric Conjugate Addition to α-Alkylidene CycloalkanonesGarcia, Pierre; Germain, Nicolas; Woodward, Simon; Alexakis, Alexandre;
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Design and Synthesis of Mixed Oligomers with Thiophenes, Dithienothiophene S,S-Dioxides, Thieno[3,4]pyrazines and 2,1,3-Benzothiadiazoles: Flipper Screening for Mechanosensitive SystemsVerolet, Quentin; Soleimanpour, Saeideh; Fujisawa, Kaori; Dal Molin, Marta; ... Matile, Stefan
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DNA display of fragment pairs as a tool for the discovery of novel biologically active small moleculesDaguer, Jean Pierre; Zambaldo, Claudio; Ciobanu, Mihail; Morieux, Pierre; ... Winssinger, Nicolas
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DNA display of glycoconjugates to emulate oligomeric interactions of glycansNovoa, Alexandre; Winssinger, Nicolas;
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Electrogenerated Chemiluminescence of Cationic Triangulene Dyes: Crucial Influence of the Core HeteroatomsAdam, Catherine; Wallabregue, Antoine; Li, Haidong; Gouin, Jérôme; ... Sojic, Neso
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Electron-deficient fullerenes in triple-channel photosystemsLópez-Andarias, Javier; Bolag, Alatengbaolige; Nancoz, Christoph; Vauthey, Eric; ... Matile, Stefan
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Enantioselective Halogenative Semi-Pinacol Rearrangement: Extension of Substrate Scope and Mechanistic InvestigationsRomanov Michailidis, Fedor; Romanova Michailidi, Maria; Pupier, Marion; Alexakis, Alexandre;
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Enolate Stabilization by Anion-π Interactions: Deuterium Exchange in Malonate Dilactones on π-Acidic SurfacesMiros, François; Zhao, Yingjie; Sargsyan, Gevorg; Pupier, Marion; ... Matile, Stefan
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Exploiting the phase of NMR signals to carry useful information. Application to the measurement of chemical shifts in aliased 2D spectraRamirez Gualito, Karla Elizabeth; Jeannerat, Damien;
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Fluorescent Flippers for Mechanosensitive Membrane ProbesDal Molin, Marta; Verolet, Quentin; Colom Diego, Adai; Letrun, Romain; ... Matile, Stefan
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Formation of Contiguous Quaternary and Tertiary Stereocenters by Sequential Asymmetric Conjugate Addition of Grignard Reagents to 2-Substituted Enones and Mg-Enolate TrappingGermain, Nicolas; Alexakis, Alexandre;
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HSP90 inhibition as a means of radiosensitizing resistant, aggressive soft tissue sarcomasErnst, Anne; Anders, Heike; Kapfhammer, Heidi; Orth, Michael; ... Lauber, Kirsten
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Identification of Covalent Bromodomain Binders through DNA Display of Small MoleculesDaguer, Jean Pierre; Zambaldo, Claudio; Abegg, Daniel; Barluenga Badiola, Sofia; ... Winssinger, Nicolas
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Improvements and Applications of the Transition Metal-Free Asymmetric Allylic Alkylation using Grignard Reagents and Magnesium AlanatesGrassi, David; Alexakis, Alexandre;
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In cellulo protein labelling with Ru-conjugate for luminescence imaging and bioorthogonal photocatalysisSadhu, Kalyan Kumar; Lindberg, Eric; Winssinger, Nicolas;
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Ion Pair−π InteractionsFujisawa, Kaori; Humbert-Droz, Marie; Letrun, Romain; Vauthey, Eric; ... Matile, Stefan
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Mechanosensitive Membrane ProbesDal Molin, Marta; Verolet, Quentin; Soleimanpour, Saeideh; Matile, Stefan;
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Modulation of Active Sites in Supported Au38 (SC2H4Ph)24 Cluster Catalysts: Effect of Atmosphere and Support MaterialZhang, Bei; Kaziz, Sameh; Li, Houhua; Hevia, Miguel González; ... Barrabes Rabanal, Noëlia
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Mononuclear Iron(III) Complexes as Functional Models of Catechol Oxidases and CatalasesBadetti, Elena; Gjoka, Blerina; Nagy, Eszter Márta; Bernardinelli, Gérald Hugues; ... Licini, Giulia
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New prostaglandin analog formulation for glaucoma treatment containing cyclodextrins for improved stability, solubility and ocular toleranceRodriguez Aller, Marta Ruth; Guinchard, Sylvie; Guillarme, Davy; Pupier, Marion; ... Gurny, Robert
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